Research Articles
Here we present our publications in specialized journals and media since 2015. It is a summary of all our work in the various research lines we have been conducting from the laboratory.
2023
284
Dimeric tetrabromo-p-quinodimethanes: synthesis and structural/electronic properties
J., Casado, Vicent, D.J., Perez-Escribano, M, Cardenas-Valdivia, A., Barragan, A., Calbo, J., Urgel, J.I., Ecija, D., Santos, J., OrtÍ, E., Martín, N.
283
77% Photothermal Conversion in Blatter-Type Diradicals: Photophysics and Photodynamic Applications
Casado, J., Ji, Y., Moles Quintero, S., Dai, Y., Marín-Beloqui, J.M., Zhang, H., Zhan, Q., Sun, F., Wang, D., Li, X., Wang, Z., Gu, X., Negri, F., Zheng, Y.
ANGEWANDTE CHEMIE - INTERNATIONAL EDITION, .DOI: 10.1002/anie.202311387
282
A Single-Crystal Monomer to Single-Crystal Polymer Reaction Activated by a Triplet Excimer in a Zipper Mechanism
Casado, J., Long, L., Medina Rivero, S., Sun, F., Wang, D., Chekulaev, D., Tonnelé, C., Casanova, D., Zheng, Y.
281
Paradromic molecules
Casado, J., Miao, Q.
NATURE SYNTHESIS, 2023, 2 (9), pp. 808-810. DOI: 10.1038/s44160-023-00320-8
280
Dimerization of a Reactive Azaacene Diradical: Synthesis of a Covalent Azaacene Cage
J., Casado, J., Fuchs, K., Medina Rivero, S., Weidlich, A., Rominger, F., Israel, N., Popov, A.A., Dreuw, A., Freudenberg, Bunz, U.H.F.
279
Ambipolar Charge Transport in Organic Semiconductors: How Intramolecular Reorganization Energy Is Controlled by Diradical Character
Casado, J., Dai, Y., Zerbini, A., Negri, F.
MOLECULES, 2023, 28 (12), art. no. 4642, DOI: 10.3390/molecules28124642
278
Helical Bilayer Nanographenes: Impact of the Helicene Length on the Structural, Electrochemical, Photophysical, and Chiroptical Properties
Casado, J., Izquierdo-García, P., Fernández-García, J.M., Medina Rivero, S., Šámal, M., Rybáček, J., Bednárová, L., Ramírez-Barroso, S., Ramírez, F.J., Rodríguez, R., Perles, J., García-Fresnadillo, D., Crassous, J., Stará, I.G., Martín, N.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2023, 145 (21), pp. 11599-11610. DOI: 10.1021/jacs.3c01088
277
Rational design of anti-Kasha photoemission from a biazulene core embedded in an antiaromatic/aromatic hybrid
Casado, J., Diaz-Andres, A., Marín-Beloqui, J., Wang, J., Liu, J., Casanova, D.
CHEMICAL SCIENCE, 14 (23), pp. 6420-6429. DOI: 10.1039/d3sc00405h
276
Quasi-Free Electron States Responsible for Single-Molecule Conductance Enhancement in Stable Radical
Casado, J., Yang, X., Hou, S., Su, M., Zhan, Q., Zhang, H., Quintero, S.M., Liu, X., Liu, J., Hong, W., Wu, Q., Lambert, C.J., Zheng, Y.
275
Asymmetric and zwitterionic Blatter diradicals
Casado, J., Miao, F., Ji, Y., Han, B., Quintero, S.M., Chen, H., Xue, G., Cai, L., Zheng, Y.
CHEMICAL SCIENCE, 2023, 14 (10), pp. 2698-2705, DOI: 10.1039/d3sc00367a.
274
Orbital Nature of Carboionic Monoradicals Made from Diradicals
Casado, J., Valdivia, A.C., Dai, Y., Rambaldi, F., Barker, J.E., Dressler, J.J., Zhou, Z., Zhu, Y., Wei, Z., Petrukhina, M.A., Haley, M.M., Negri, F.
CHEMISTRY - A EUROPEAN JOURNAL, 2023, 29, 27, e202300388, DOI: 10.1002/chem .202300388.
273
Synthesis of a Dicyclohepta[a,g]heptalene-Containing Polycyclic Conjugated Hydrocarbon and the Impact of Non-Alternant Topologies
Casado, J., Wang, J., Gámez, F.G., Marín-Beloqui, J., Diaz-Andres, A., Miao, X., Casanova, D., Liu, J.
2022
272
Polycyclic Hydrocarbons from [4n]Annulenes: Correlation versus Hybridization Forces in the Formation of Diradicaloids
Casado, J., Moles Quintero, S., Haley, M.M., Kertesz, M.
ANGEWANDTE CHEMIE - INTERNATIONAL EDITION, 2022, 61 (44), art. no. e202209138
271
Medium Diradical Character, Small Hole and Electron Reorganization Energies and Ambipolar Transistors in Difluorenoheteroles
Casado, J., Mori, S., Moles Quintero, S., Tabaka, N., Kishi, R., González Núñez, R., Harbuzaru, A., Ponce Ortiz, R., Marín-Beloqui, J., Suzuki, S., Kitamura, C., Gómez-García, C.J., Dai, Y., Negri, F., Nakano, M., Kato, S.-I.
ANGEWANDTE CHEMIE - INTERNATIONAL EDITION, 2022, 61 (33), art. no. e202206680
270
Simultaneous Detection of Circularly Polarized Luminescence and Raman Optical Activity in an Organic Molecular Lemniscate
Casado, J., Palomo, L., Favereau, L., Senthilkumar, K., Stępień, M., Ramírez, F.J.
ANGEWANDTE CHEMIE - INTERNATIONAL EDITION 2022, DOI: 10.1002/anie.202206976
269
The smallest oligothiophene diradicals by asymmetric substitution of quinoidal cores
Casado, J., Wang, K., Zhan, Q., Han, B., Quintero, S.M., Huang, W., Ji, Y., Miao, F., Chen, H., Zheng, Y.
JOURNAL OF MATERIALS CHEMISTRY C, 2022, 10 (35), pp. 12724-12730
268
Raman Activities of Cyano-Ester Quinoidal Oligothiophenes Reveal Their Diradical Character and the Proximity of the Low-Lying Double Exciton State
Casado, J., Dai, Y., Bonometti, L., Zafra, J.L., Takimiya, K., Negri, F.
267
Vibrational Raman Spectroscopy of Diradicaloids. Revealing Their Physical Origin
Casado, J., Medina Rivero, S., Zafra, J.L.
266
Molecular and Spin Structures of a Through-Space Conjugated Triradical System
Casado, J., Kodama, T., Aoba, M., Hirao, Y., Rivero, S.M., Kubo, T.
ANGEWANDTE CHEMIE - INTERNATIONAL EDITION, 2022, 61 (14), 202200688.
265
Strain Switching in van der Waals Heterostructures Triggered by a Spin-Crossover Metal–Organic Framework
Casado, J., Boix-Constant, C., García-López, V., Navarro-Moratalla, E., Clemente-León, M., Zafra, J.L., Guinea, F., Mañas-Valero, S., Coronado, E.
264
Cross-conjugated isothianaphthene quinoids: a versatile strategy for controlling electronic structures
Casado, J., Yamamoto, K., Quintero, S.M., Jinnai, S., Jeong, E., Matsuo, K., Suzuki, M., Yamada, H., Ie, Y.
2021
263
Near-Infrared Lasing in Four-Zigzag Edged Nanographenes by 1D versus 2D Electronic π-Conjugation
J., Casado, Muñoz-Mármol, R., Gordillo, F., Bonal, V., Villalvilla, J.M., Boj, P.G., Quintana, J.A., Ross, A.M., Paternò, G.M., Scotognella, F., Lanzani, G., Derradji, A., Sancho-García, J.C., Gu, Y., Wu, J., Díaz-García, M.A.
262
Oligoene and cyanine features of tetracyano quinoidal oligothiophenes
J., Casado, Moles Quintero, S., Zafra, J.L., Yamamoto, K., Aso, Y., Ie, Y.
261
A nitrogen-doped asymmetric phenalenyl with a zwitterionic ground state
J., Casado, Miao, F., Chen, H., Moles Quintero, S., Xue, G., Zheng, Y.
260
A Trapezoidal Octacyanoquinoid Acceptor Forms Solution and Surface Products by Antiparallel Shape Fitting with Conformational Dipole Momentum Switch
J., Casado, Medina Rivero, S., Urieta-Mora, J., Molina-Ontoria, A., Martín-Fuentes, C., Urgel, J.I., Zubiria-Ulacia, M., Lloveras, V., Casanova, D., Martínez, J.I., Veciana, J., Écija, D., Martín, N.
ANGEWANDTE CHEMIE - INTERNATIONAL EDITION, 2021, 60 (33), 17887-17892
259
Normal & reversed spin mobility in a diradical by electron-vibration coupling
J., Casado, Shen, Y., Xue, G., Dai, Y., Quintero, S.M., Chen, H., Wang, D., Miao, F., Negri, F., Zheng, Y.
258
Raman and ROA analyses of twisted anthracenes: connecting vibrational and electronic/photonic structures
J., Casado, Palomo, L., Gordillo Gámez, F., Bedi, A., Gidron, O., Ramírez, F.J.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2021, 23 (25), 13996-14003
257
Non-Aufbau Spiro-Conjugated Quinoidal & Aromatic Charged Radicals
J., Casado, Medina Rivero, S., Shang, R,, Hamada, H., Yan, Q., Tsuji, H., Nakamura, E.
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2021, 94 (3), 989-996
256
Single-Molecule Conductance in a Unique Cross-Conjugated Tetra(Aminoaryl)-Ethene
J., Casado, Medina Rivero, S., García Arroyo, P., Li, L., Gunasekaran, S., Stuyver, T., Mancheño, M.J., Alonso, M., Venkataraman, L., Segura, J.L.
2020
255
Monoradicals and Diradicals of Dibenzofluoreno[3,2- b]fluorene Isomers: Mechanisms of Electronic Delocalization
J., Casado, Hayashi, H., Barker, J.E., Cárdenas Valdivia, A., Kishi, R., Macmillan, S.N., Gómez-García, C.J., Miyauchi, H., Nakamura, Y., Nakano, M., Kato, S.-I., Haley, M.M.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2020, 142, 20444-20455
254
Synthesis and electronic properties of pyridine end-capped cyclopentadithiophene-vinylene oligomers
J., Casado, Guijarro, F.G., Medina Rivero, S., Gunasekaran, S., Arretxea, I., Ponce Ortiz, R., Caballero, R., De La Cruz, P., Langa, F., Venkataraman, L.
253
The loss of endgroup effects in long pyridyl-endcapped oligoynes on the way to carbyne
Juan Casado, Yueze Gao; Yuxuan Hou; Fernando Gordillo-Gámez; Mike Ferguson; Rik R. Tykwinski.
252
A Chichibabin's Hydrocarbon-Based Molecular Cage: The Impact of Structural Rigidity on Dynamics, Stability, and Electronic Properties
Casado, Juan; Ni, Yong; Gordillo-Gamez, Fernando; Alvarez, Miriam Pena; Nan, Zhihan; Li, Zhengtao; Wu, Shaofei; Han, Yi; Wu, Jishan
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2020, 142, 12730-12742
251
The New "Noble Gas'' Molecule: A Molecular Trip beyond Atoms
Casado, Juan; Martin, Nazario.
250
Perylene-Fused, Aggregation-Free Polycyclic Aromatic Hydrocarbons for Solution-Processed Distributed Feedback Lasers
Casado, Juan; Zou, Ya; Bonal, Victor; Moles Quintero, Sergio; Boj, Pedro G.; Villalvilla, Jose M.; Quintana, Jose A.; Li, Guangwu; Wu, Shaofei; Jiang, Qing; Ni, Yong; Diaz-Garcia, Maria A.; Wu, Jishan
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2020, 59, 14927-14934
249
Diindenoanthracene Diradicaloids Enable Rational, Incremental Tuning of Their Singlet-Triplet Energy Gaps
Casado, Juan; Dressler, Justin J.; Cardenas Valdivia, Abel; Kishi, Ryohei; Rudebusch, Gabriel E.; Ventura, Austin M.; Chastain, Brian E.; Gomez-Garcia, Carlos J.; Zakharov, Lev N.; Nakano, M.; Haley, Michael M.
248
Raman Optical Activity (ROA) as a New Tool to Elucidate the Helical Structure of Poly(phenylacetylene)s
Casado, Juan; Palomo, Luis; Rodriguez, Rafael; Medina, Samara; Quinoa, Emilio; Freire, Felix; Ramirez, Francisco J.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2020, 59, 9080-9087
247
Cove-Edged Nanographenes with Localized Double Bonds
Casado, Juan; Gu, Yanwei; Munoz-Marmol, Rafael; Wu, Shaofei; Han, Yi; Ni, Yong; Diaz-Garcia, Maria A.; Wu, Jishan
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2020, 59, 8113-8117
246
Aromatic Nanosandwich Obtained by sigma-Dimerization of a Nanographenoid pi-Radical
Casado, Juan; Moshniaha, Liliia; Zyla-Karwowska, Marika; Chmielewski, Piotr J.; Lis, Tadeusz; Cybinska, Joanna; Gonka, Elibieta; Oschwald, Johannes; Drewello, Thomas; Medina Rivero, Samara; Stepien, Marcin
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2020,142, 3626-3635
245
Molecule Isomerism Modulates the Diradical Properties of Stable Singlet Diradicaloids
Casado, Juan; Barker, Joshua E.; Dressler, Justin J.; Cardenas Valdivia, Abel; Kishi, Ryohei; Strand, Eric T.; Zakharov, Lev N.; MacMillan, Samantha N.; Gomez-Garcia, Carlos J.; Nakano, Masayoshi; Haley, Michael M.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2020, 142,1548-1555
2019
244
243
Fluoreno[2,1-a]fluorene: an ortho-naphthoquinodimethane-based system with partial diradical character
Casado, Juan; Hacker, Allison S.; Pavano, Mauricio; Wood, James E., II; Hashimoto, Hannah; D'Ambrosio, Kyle M.; Frederickson, Conerd K.; Zafra, Jose. L.; Gomez-Garcia, Carlos J.; Postils, Veronica; McDonald, Ashley Ringer; Casanova, David; Frantz, Derik K.
242
Two-electron transfer stabilized by excited-state aromatization
Casado, Juan; Kim, Jinseok; Oh, Juwon; Park, Seongchul; Zafra, Jose L.; DeFrancisco, Justin R.; Casanova, David; Lim, Manho; Tovar, John D.; Kim, Dongho.
241
Linear, Non-Conjugated Cyclic and Conjugated Cyclic Paraphenylene under Pressure
Casado, Juan; Pena-Alvarez, Miriam; Fanetti, Samuele; Falsini, Naomi; Novelli, Giulia; Baonza, Valentin G.; Taravillo, Mercedes; Parsons, Simon; Bini, Roberto; Citroni, Margherita
240
Molecules under Pressure: The Case of [n]Cycloparaphenylenes
Casado, Juan; Pena-Alvarez, Miriam; Qiu, Lili; Baonza, Valentin G.; Taravillo, Mercedes; Kertesz, Miklos.
239
Perylene-Fused, Aggregation-Free Polycyclic Aromatic Hydrocarbons for Solution-Processed Distributed Feedback Lasers
Casado, Juan; Burrezo, Paula Mayorga; Zeng, Wangdong; Moos, Michael; Holzapfel, Marco; Canola, Sofia; Negri, Fabrizia; Rovira, Concepcio; Veciana, Jaume; Hoa Phan; Wu, Jishan; Lambert, Christoph.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2019, 58, 14467-14471
238
Stable Cross-Conjugated Tetrathiophene Diradical
Casado, Juan; Zhang, Cheng; Medina Rivero, Samara; Liu, Wuyue; Casanova, David; Zhu, Xiaozhang.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2019, 58, 11291-11295
237
Solution-processed nanographene distributed feedback lasers
Casado, Juan; Bonal, Victor; Munoz-Marmol, Rafael; Gordillo Gamez, Fernando; Morales-Vidal, Marta; Villalvilla, Jose M.; Boj, Pedro G.; Quintana, Jose A.; Gu, Yanwei; Wu, Jishan; Diaz-Garcia, Maria A.
236
Singlet fission in spiroconjugated dimers
Casado, Juan; Sandoval-Salinas, Maria E.; Carreras, Abel; Casanova, David
235
Lemniscular [16]Cycloparaphenylene: A Radially Conjugated Figure-Eight Aromatic Molecule
Casado, Juan; Senthilkumar, Kabali; Kondratowicz, Mateusz; Lis, Tadeusz; Chmielewski, Piotr J.; Cybinska, Joanna; Zafra, Jose L.; Vives, Thomas; Crassous, Jeanne; Favereau, Ludovic; Stepien, Marcin.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2019, 141,7421-7427
234
Long rylene nanoribbons express polyacetylene-like signatures at their edges
Casado, Juan; Medina Rivero, Samara; Canola, Sofia; Zeng, Wangdong; Ramirez, Francisco J.; Zafra, Jose L.; Wu, Jishan; Negri, Fabrizia.
233
Cholesteric Aggregation at the Quinoidal-to-Diradical Border Enabled Stable n-Doped Conductor
Casado, Juan; Yuan, Dafei; Huang, Dazhen; Rivero, Samara Medina; Carreras, Abel; Zhang, Cheng; Zou, Ye; Jiao, Xuechen; McNeill, Christopher R.; Zhu, Xiaozhang; Di,Chong-an; Zhu, Daoben; Casanova, David.
232
Charge transport modulation in pseudorotaxane 1D stacks of acene and azaacene derivatives
Casado, Juan; Gozalvez, Cristian; Zafra, Jose L.; Saeki, Akinori; Melle-Franco, Manuel; Mateo-Alonso, Aurelio
231
[All]-S,S-dioxide Oligo-Thienylenevinylenes: Synthesis and Structural/Electronic Shapes from Their Molecular Force Fields
Casado, Juan; Aharon, Cheryl; Guijarro, Fernando G.; Rivero, Samara Medina; Ramirez, Francisco J.; Caballero, Ruben; Langa, Fernando; Rozen, Shlomo.
2018
230
pi-Extended Corannulene-Based Nanographenes: Selective Formation of Negative Curvature
Casado, Juan; Fernandez-Garcia, Jesus M.; Evans, Paul J.; Rivero, Samara Medina; Fernandez, Israel; Garcia-Fresnadillo, David; Perles, Josefina; Martin, Nazario.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2018, 140, 17188-17196
229
Thiophene and its sulfur inhibit indenoindenodibenzothiophene diradicals from low-energy lying thermal triplets
Casado, Juan; Dressler, Justin J.; Teraoka, Mitsuru; Espejo, Guzman L.; Kishi, Ryohei; Takamuku, Shota; Gomez-Garcia, Carlos J.; Zakharov, Lev N.; Nakano, Masayoshi; Haley, Michael M.
228
Redox-Active Chiroptical Switching in Mono- and Bis-Iron Ethynylcarbo[6]helicenes Studied by Electronic and Vibrational Circular Dichroism and Resonance Raman Optical Activity
Casado, Juan; Shen, Chengshuo; Srebro-Hooper, Monika; Weymuth, Thomas; Krausbeck, Florian; Lopez Navarrete, Juan T.; Ramirez, Francisco J.; Nieto-Ortega, Belen; Reiher, Markus; Autschbach, Jochen; Crassous, Jeanne.
227
The double exciton state of conjugated chromophores with strong diradical character: insights from TDDFT calculations
Casado, Juan; Canola, Sofia; Negri, Fabrizia
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2018, 20, 37, 24227-24238
226
Thieno[3,4-c]pyrrole-4,6-dione Oligothiophenes Have Two Crossed Paths for Electron Delocalization
Casado, Juan; Yuan, Dafei; Medina Rivero, Samara; Mayorga Burrezo, Paula; Ren, Longbin; Sandoval-Salinas, Maria E.; Grabowski, Slawomir J.; Casanova, David; Zhu, Xiaozhang.
225
Breathing-Dependent Redox Activity in a Tetrathiafulvalene-Based Metal-Organic Framework
Casado, Juan; Souto, Manuel; Romero, Jorge; Calbo, Joaquin; Vitórica-Yrezábal, Íñigo J.; Zafra, Jose L.; Ortí, Enrique; Walsh, Aron; Mínguez Espallargas, Guillermo
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2018, 140, 10562-10569
224
Mechanochemistry in [6]Cycloparaphenylene: A Combined Raman Spectroscopy and Density Functional Theory Study
Casado, Juan; Qiu, Lili; Pena-Alvarez, Miriam; Baonza, Valentin G.; Taravillo, Mercedes; Kertesz, Miklos
223
Chemistry and spectroscopy of cross-conjugated and pseudo-cross-conjugated quinolinium-ethynyl-benzoate mesomeric betaines
Casado, Juan; Batsyts, Sviatoslav; Ramirez, Francisco J.; Namyslo, Jan C.; Schmidt, Andreas
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2018, 73. 481-491
222
Isomerism, Diradical Signature, and Raman Spectroscopy: Underlying; Connections in Diamino Oligophenyl Dications
Casado, Juan; Medina Rivero, Samara; Mayorga Burrezo, Paula; Eugenia Sandoval-Salinas, Maria; Li, Tao; Ramirez, Francisco J.; Casanova, David; Wang, Xinping.
221
Torsional Bias as a Strategy To Tune Single-triplet Gaps in Organic Diradicals
Casado, Juan; DeFrancisco, Justin R.; Lopez-Espejo, Guzman; Zafra, Jose Luis; Yadav, Sangeeta; Messersmith, Reid E.; Gomez-Garcia, Carlos J.; Ottosson, Henrik; Tovar, John D.
220
Sequential Induction of Chirality in Helical Polymers: From the Stereocenter to the Achiral Solvent
Casado, Juan; Nieto-Ortega, Belen; Rodriguez, Rafael; Medina, Samara; Quinoa, Emilio; Riguera, Ricardo; Freire, Felix; Javier Ramirez, Francisco
219
Stable Nitrogen-Centered Bis(imino)rylene Diradicaloids
Casado, Juan; Zeng, Wangdong; Hong, Yongseok; Medina Rivero, Samara; Kim, Jinseok; Zafra, Jose L.; Phan, Hoa; Gopalakrishna, Tullimilli Y.; Herng, Tun Seng; Ding, Jun; Kim, Dongho; Wu, Jishan
218
Oligothienylenevinylene Polarons and Bipolarons Confined between Electron-Accepting Perchlorotriphenylmethyl Radicals
Casado, Juan; Mayorga Burrezo, Paula; Franco, Carlos; Caballero, Ruben; Mas-Torrent, Marta; Langa, Fernando; Lopez Navarrete, Juan T.; Rovira, Concepcio; Veciana, Jaume
217
Breaking Bonds and Forming Nanographene Diradicals with Pressure
Casado, Juan; Desroches, Maude; Mayorga Burrezo, Paula; Boismenu-Lavoie, Joel; Pena Alvarez, Miriam; Gomes-Garcia, Carlos J.; Matxain, Jon M.; Casanova, David; Morin, Jean-Francois.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2018, 56,16212-16217
2017
216
Algunas reflexiones curiosas en el aula sobre el equilibrio químico de una reacción
Casado, Juan.
215
Even and odd oligothiophene-bridged bis-naphthalimides for n-type and ambipolar organic field effect transistors
Casado, J., Riano Carnerero, A., Lopez Espejo, G., Mancheno Real, M. J., Eckstein, B., Gonzalez-Cano, R. C., Melkonyan, F. S., Facchetti, A., Marks, T. J., Lopez Navarrete, J. T., Segura, J. L., Ponce Ortiz, R.
214
Oligomers of cyclopentadithiophene-vinylene in aromatic and quinoidal versions and redox species with intermediate forms
Casado, Juan; Mayorga Burrezo, Paula; Dominguez, Rocio; Zafra, Jose L.; Pappenfus, Ted M.; de la Cruz, Pilar; Welte, Lorena; Janzen, Daron E.; Lopez Navarrete, Juan T.; Langa, Fernando.
213
High-Pressure Chemistry and the Mechanochemical Polymerization of [5]-Cyclo-p-phenylene
Casado, Juan; Qiu, Lili; Pena-Alvarez, Miriam; Taravillo, Mercedes; Evans, Paul J.; Darzi, Evan R.; Jasti, Ramesh; Mayorga Burrezo, P.; Lopez Navarrete, Juan T.; Baonza, Valentin G.; Kertesz, Miklos.
212
Carbon-Bridged Phenylene-Vinylenes: On the Common Diradicaloid Origin of Their Photonic and Chemical Properties
Casado, Juan; Gonzalez-Cano, Rafael C.; Di Motta, Simone; Zhu, Xiaozhang; Lopez Navarrete, Juan. T.; Tsuji, Hayato; Nakamura, Eiichi; Negri, Fabrizia.
211
Solvent-Directed Helical Stereomutation Discloses Pathway Complexity on N-Heterotriangulene-Based Organogelators
Casado, Juan; Valera, Jorge S.; Sanchez-Naya, Roberto; Ramirez, Francisco J.; Zafra, Jose L.; Gomez, Rafael; Sanchez, Luis.
210
Para-Quinodimethanes: A Unified Review of the Quinoidal-Versus-Aromatic Competition and its Implications
Casado, Juan.
209
Push-Pull-Type Polychlorotriphenylmethyl Radicals: New Two-Photon Absorbers and Dyes for Generation of Photo-Charges
Casado, Juan; Wu, Xiaojin; Kim, Jun Oh; Medina, Samara; Ramirez, Francisco J.; Burrezo, Paula Mayorga; Wu, Shaofei; Lim, Zheng Long; Lambert, Christoph; Kim, Dongho; Wu, Jishan
208
Ambient Stable Radical Cations, Diradicaloid pi-Dimeric Dications, Closed-Shell Dications, and Diradical Dications of Methylthio-Capped Rylenes
Casado, Juan; Qi, Qingbiao; Burrezo, Paula Mayorga; Hoa Phan; Herng, Tun Seng; Gopalakrishna, Tullimilli Y.; Zeng, Wangdong; Ding, Jun; Wu, Jishan
207
Dithienyl Acenedithiophenediones as New π-Extended Quinoidal Cores: Synthesis and Properties
Casado, Juan; Kawabata, Kohsuke; Osaka, Itaru; Sawamoto, Masanori; Zafra, Jose L.; Mayorga Burrezo, Paula; Takimiya, Kazuo
206
Bis(aminoaryl) Carbon-Bridged Oligo(phenylenevinylene)s Expand the Limits of Electronic Couplings
Casado, Juan; Mayorga Burrezo, Paula; Lin, Nai-Ti; Nakabayashi, Koji; Ohkoshi, Shin-ichi; Calzado, Eva M.; Boj, Pedro G.; Diaz Garcia, Maria A.; Franco, Carlos; Rovira, Concepcio; Veciana, Jaume; Moos, Michael; Lambert, Christoph; Lopez Navarrete, Juan T.; Tsuji, Hayato; Nakamura, Eiichi.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2017, 56, 2898-2902
205
Fingerprints of Through-Bond and Through-Space Exciton and Charge π‑Electron Delocalization in Linearly Extended [2.2]Paracyclophanes
Casado, Juan; Zafra, Jose L.; Molina Ontoria, Agustin; Mayorga Burrezo, Paula; Pena-Alvarez,Miriam; Samoc, Marek; Szeremeta, Janusz; Ramirez, Francisco J.; Lovander, Matthew D.; Droske, Christopher J.; Pappenfus, Ted M.; Echegoyen, Luis; Lopez Navarrete, Juan T.; Martin, Nazario.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2017, 139, 3095-3105
204
Quinoidal/Aromatic Transformations in pi-Conjugated Oligomers: Vibrational Raman studies on the Limits of Rupture for pi-Bonds
Casado, Juan; Mayorga Burrezo, Paula; Zafra, Jose L.; Lopez Navarrete, Juan T.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2017, 56, 2250-2259
203
Operative Mechanism of Hole-Assisted Negative Charge Motion in Ground States of Radical-Anion Molecular Wires
Casado, Juan; Franco, Carlos; Mayorga Burrezo, Paula; Lloveras, Vega; Caballero, Ruben; Alcon, Isaac; Bromley, Stefan T.; Mas-Torrent, Marta; Langa, Fernando; Lopez Navarrete, Juan T.; Rovira, Concepcio; Veciana, Jaume
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2017, 139, 686-692
202
Formation of complexes between functionalized chitosan membranes and copper: A study by angle resolved XPS
Casado, Juan; Jurado-Lopez, Belen; Vieira, Rodrigo Silveira; Rabelo, Rodrigo Balloni; Beppu, Marisa Masumi; Rodriguez-Castellon, Enrique
2016
201
Reversible Dimerization and Polymerization of a Janus Diradical Tom Produce Labile C-C Bonds and Large Chromic Effects
Casado, Juan; Zafra, Jose L.; Qiu, Lili; Yanai, Naoyuki; Mori, Takamichi; Nakano, Masahiro; Pena Alvarez, Miriam; Lopez Navarrete, Juan T.; Gomez-Garcia, Carlos J.; Kertesz, Miklos; Takimiya, Kazuo.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2016, 55, 14563-14568
200
Extending Hexaazatriphenylene with Mono-/Bithiophenes in Acceptor-Donor Diads and Acceptor-Donor-Acceptor Triads
Casado, Juan; Moreno Oliva, Maria; Riano, Alberto; Arrechea-Marcos, Iratxe; Ramos, Maria M.; Gomez, Rafael; Algarra, Manuel; Ponce Ortiz, Rocio; Lopez Navarrete, Juan T.; Segura, Jose L.;.
199
A Biradical Balancing Act: Redox Amphoterism in a Diindenoanthracene Derivative Results from Quinoidal Acceptor and Aromatic Donor Motifs
Casado, Juan; Rudebusch, Gabriel E.; Espejo, Guzman L.; Zafra, Jose L.; Pena-Alvarez, Miriam; Spisak, Sarah N.; Fukuda, Kotaro; Wei, Zheng; Nakano, Masayoshi; Petrukhina, Marina A.; Haley, Michael M.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2016, 138, 12648-12654
198
Diindeno-fusion of an anthracene as a design strategy for stable organic biradicals
Casado, Juan; Rudebusch, Gabriel E.; Zafra, Jose L.; Jorner, Kjell; Fukuda, Kotaro; Marshall, Jonathan L.; Arrechea-Marcos, Iratxe; Espejo, Guzman L.; Ponce Ortiz, Rocio; Gomez-Garcia, Carlos J.; Zakharov, Lev N.; Nakano, Masayoshi; Ottosson, Henrik; Haley, Michael M.
197
Iron Alkynyl Helicenes: Redox-Triggered Chiroptical Tuning in the IR and Near-IR Spectral Regions and Suitable for Telecommunications Applications
Casado, Juan; Shen, Chengshuo; Loas, Goulc'hen; Srebro-Hooper, Monika; Vanthuyne, Nicolas; Toupet, Loic; Cador, Olivier; Paul, Frederic; Lopez Navarrete, Juan T.; Ramirez, Francisco J.; Nieto-Ortega, Belen; Autschbach, Jochen; Vallet, Marc; Crassous, Jeanne
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2016, 55, 8062-8066
196
Fully Fused Quinoidal/Aromatic Carbazole Macrocycles with Poly-radical Characters
Casado, Juan; Das, Soumyajit; Herng, Tun Seng; Zafra, Jose L.; Burrezo, Paula Mayorga; Kitano, Masaaki; Ishida, Masatoshi Y.; Gopalakrishna, Tullimilli Y.; Hu, Pan; Osuka, Atsuhiro; Ding, Jun; Casanova, David; Wu, Jishan
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2016 138, 7782-7790
195
From linear to cyclic oligoparaphenylenes: electronic and molecular changes traced in the vibrational Raman spectra and reformulation of the bond length alternation pattern
Casado, Juan; Pena-Alvarez, Miriam; Qiu, Lili; Taravillo, Mercedes; Baonza, Valentin G.; Ruiz Delgado, M. Carmen; Yamago, Shigeru; Jasti, Ramesh; Lopez Navarrete, Juan T.; Kertesz, Miklos
194
Benzotrithiophene versus Benzo/Naphthodithiophene Building Blocks: The Effect of Star-Shaped versus Linear Conjugation on Their Electronic Structures
Casado, Juan; Riano, Alberto; Arrechea-Marcos, Iratxe; Mancheno, Maria J.; Mayorga Burrezo, Paula; de la Pena, Alejandro; Loser, Stephen; Timalsina, Amod; Facchetti, Antonio; Marks, Tobin J.; Teodomiro Lopez Navarrete, J.; Ponce Ortiz, Rocio; Segura, Jose L.
193
The Raman fingerprint of cyclic conjugation: the case of the stabilization of cations and dications in cycloparaphenylenes
Casado, Juan; Pena Alvarez, Miriam; Ruiz Delgado, M. Carmen; Taravillo, Mercedes; Baonza, Valentin G.; Lopez Navarrete, Juan T.; Evans, Paul; Jasti, Ramesh; Yamago, Shigeru; Kertesz, Miklos.
192
Benzo-thia-fused [n]thienoacenequinodimethanes with small to moderate diradical characters: the role of pro-aromaticity versus anti-aromaticity
Casado, Juan; Shi, Xueliang; Quintero, Estefania; Lee, Sangsu; Jing, Linzhi; Herng, Tun Seng; Zheng, Bin; Huang, Kuo-Wei; Navarrete, Juan T. Lopez; Ding, Jun; Kim, Dongho; Chi, Chunyan
2015
191
D−π–A Compounds with Tunable Intramolecular Charge Transfer Achieved by Incorporation of Butenolide Nitriles as Acceptor Moieties
Casado, Juan; Moreno-Yruela, Carlos; Garin, Javier; Orduna, Jesus; Franco, Santiago; Quintero, Estefania; Lopez Navarrete, Juan T.; Diosdado, Beatriz E.; Villacampa, Belen; Andreu, Raquel.
190
Vibrational Raman Shifts and Aromaticity: The Case of Oligothiophenes
Casado, Juan; Hernandez, Victor; Lopez Navarrete, Juan T.
189
Carbon-bridged oligo(p-phenylenevinylene)s for photostable and broadly tunable, solution-processable thin film organic lasers
Casado, Juan; Morales-Vidal, Marta; Boj, Pedro G.; Villalvilla, Jose M.; Quintana, Jose A.; Yan, Qifan; Lin, Nai-Ti; Zhu, Xiaozhang; Ruangsupapichat, Nopporn; Tsuji, Hayato; Nakamura, Eiichi; Diaz-Garcia, Maria A.
188
Multifaceted Regioregular Oligo(thieno[3,4-b]thiophene)s Enabled by Tunable Quinoidization and Reduced Energy Band Gap
Casado, Juan; Liu, Feng; Espejo, Guzman L.; Qin, Shuhai; Moreno Oliva, Maria; Pina, Joao;Sergio Seixas de Melo, J.; Zhu, Xiaozhang
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2015, 137, 10357-10366
187
Push-Pull Type Oligo(N-annulated perylene)quinodimethanes: Chain Length and Solvent-Dependent Ground States and Physical Properties
Casado, Juan; Zeng, Zebing; Lee, Sangsu; Son, Minjung; Fukuda, Kotaro; Mayorga Burrezo, Paula; Zhu, Xiaojian; Qi, Qingbiao; Li, Run-Wei; Lopez Navarrete, Juan T.; Ding, Jun; Nakano, Masayoshi; Kim, Dongho; Wu, Jishan
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2015, 137, 8572-8583
186
Understanding the Origin of the VCD Signals on the Basis of a Nonredundant Coordinate Definition
Casado, Juan; Nieto-Ortega, Belen; Navarrete, Juan T. Lopez; Ramirez, Francisco J.; Tommasini, Matteo; Longhi, Giovanna; Mazzeo, Giuseppe; Abbate, Sergio
JOURNAL OF CHEMICAL THEORY AND COMPUTATION, 2015, 11, 2633-2641
185
An Unusually Small Singlet-Triplet Gap in a Quinoidal 1,6-Methano[10]annulene Resulting from Baird's 4n pi-Electron Triplet Stabilization
Casado, Juan; Streifel, Benjamin C.; Zafra, Jose L.; Espejo, Guzman L.; Gomez-Garcia, Carlos J.; Tovar, John D.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015, 54, 5888-5893
184
High Yield Ultrafast Intramolecular Singlet Exciton Fission in a Quinoidal Bithiophene
Casado, Juan; Varnavski, Oleg; Abeyasinghe, Neranga; Arago, Juan; Serrano-Perez, Juan J.; Orti, Enrigue; Lopez Navarrete, Juan T.; Takimiya, Kazuo; Casanova, David; Goodson, Theodore III
183
Planarization, Fusion, and Strain of Carbon-Bridged Phenylenevinylene Oligonners Enhance pi-Electron and Charge Conjugation: A Dissectional Vibrational Raman Study
Casado, Juan; Mayorga Burrezo, Paula; Zhu, Xiaozhang; Zhu, Shou-Fei; Yan, Qifan; Lopez Navarrete, Juan T.; Tsuji, Hayato; Nakamura, Eiichi
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2015, 137, 3834-3843
182
Robust Ethylenedioxythiophene-Vinylene Oligomers from Fragile Thiophene-Vinylene Cores: Synthesis and Optical, Chemical and Electrochemical Properties of Multicharged Shapes
Casado, Juan; Mayorga Burrezo, Paula; Pelado, Beatriz; Ponce Ortiz, Rocio; De la Cruz, Pilar; Lopez Navarrete, Juan T.; Langa, Fernando
181
Polarization, second-order nonlinear optical properties and electrochromism in 4H-pyranylidene chromophores with a quinoid/aromatic thiophene ring bridge
Casado, Juan; Belen Marco, A.; Mayorga Burrezo, Paula; Mosteo, Laura; Franco, Santiago; Garin, Javier; Orduna, Jesus; Diosdado, Beatriz E.; Villacampa, Belen; Lopez Navarrete, Juan T.; Andreu, Raquel
180
Pro-aromatic and anti-aromatic pi-conjugated molecules: an irresistible wish to be diradicals
Casado, Juan; Zeng, Zebing; Shi, Xueliang; Chi, Chunyan; Lopez Navarrete, Juan T.; Wu, Jishan
179
On the handedness of helical aggregates of C-3 tricarboxamides: a multichiroptical characterization
Casado, Juan; Nieto-Ortega, Belen; Garcia, Fatima; Longhi, Giovanna; Castiglioni, Ettore; Calbo, Joaquin; Abbate, Sergio; Navarrete, Juan T. Lopez; Ramirez, Francisco J.; Orti, Enrique; Sanchez, Luis.